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Tin(II) hydroxide
・ Tin(II) iodide
・ Tin(II) oxide
・ Tin(II) sulfate
・ Tin(II) sulfide
・ Tin(IV) bromide
・ Tin(IV) chloride
・ Tin(IV) fluoride
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Tin(II) hydroxide : ウィキペディア英語版
Tin(II) hydroxide

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Tin(II) hydroxide, Sn(OH)2, also known as ''stannous hydroxide'', is a chemical compound of tin in the +2 oxidation state. Pure Sn(OH)2 is prepared by reacting for example (CH3)3SnOH with SnCl2 in an aprotic solvent:
:2 Me3SnOH + SnCl2 → Sn(OH)2 + 2 Me3SnCl
There had been confusion as it had been believed that Sn(OH)2 was precipitated when a tin(II) salt is reacted with an alkali hydroxide such as NaOH, but this product was determined analytically to be hydrated tin(II) oxide, being either 5 SnO • 2 H2O or 3 SnO • H2O.〔Structure of Tin(II) "Hydroxide" and Lead(II) "Hydroxide", R. A. Howie & W. Moser, Nature 219, 372 - 373 (27 July 1968); 〕 The structure of pure Sn(OH)2 is not known.〔
Stannous hydroxide is easily oxidized to stannic acid (SnO2) by air since tin is often found in oxidation state +4.
==References==



抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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